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There are two primary alkyl halides having the formula, C4H9Br. They are n − bulyl bromide and isobutyl bromide.
Therefore, compound (a) is either n−butyl bromide or isobutyl bromide.
Now, compound (a) reacts with Na metal to give compound (b) of molecular formula, C8H18, which is different from the compound formed when n−butyl bromide reacts with Na metal. Hence, compound (a) must be isobutyl bromide.
Thus, compound (d) is 2, 5−dimethylhexane.
It is given that compound (a) reacts with alcoholic KOH to give compound (b). Hence, compound (b) is 2−methylpropene.
Also, compound (b) reacts with HBr to give compound (c) which is an isomer of (a). Hence, compound (c) is 2−bromo−2−methylpropane.
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